Mixed-Metal Oxide Catalyst for Liquid Phase Benzene Alkylation

Friedel-Crafts alkylation of Phenol using Ionic Liquid as Catalyst

Direct oxidation of benzene to phenol in liquid phase by H2O2 over vanadium catalyst supported on highly ordered nanoporous silica

Vanadium supported on highly ordered nanoporous silica (VOx-LUS-1) was synthesized and characterized by XRD, Nitrogen adsorption‑desorption isotherms and UV-visible spectrophotometer. Direct oxidation of benzene to phenol in liquid phase by H2O2 peroxide were examined by using various solvents (methanol, acetone, acetic acid, acetonitryl). The maximum yield (25%) and selectivity (73%) of the ph...

Enantioselective Decarboxylative Alkylation Reactions: Catalyst

α-Quaternary ketones are accessed through novel enantioselective alkylations of allyl and propargyl electrophiles by unstabilized prochiral enolate nucleophiles in the presence of palladium complexes with various phosphinooxazoline (PHOX) ligands. Excellent yields and high enantiomeric excesses are obtained from three classes of enolate precursors: enol carbonates, enol silanes, and racemic β-k...

Stability, Deactivation, and Regeneration of Chloroaluminate Ionic Liquid as Catalyst for Industrial C4 Alkylation

Alkylation of isobutane and 2-butene was carried out in a continuous unit using triethylamine hydrochloride (Et3NHCl)-aluminum chloride (AlCl3) ionic liquid (IL) as catalyst. The effects of impurities such as water, methanol, and diethyl ether on the stability of the catalytic properties and deactivation of the ionic liquid were studied in the continuous alkylation. In the Et3NHCl-2AlCl3 ionic ...

Application of GA in Optimization of Modified Benzene Alkylation Process

A genetic algorithm is used to optimize the modified benzene alkylation process. Based on the previous studies, the modified process increases ethylbenzene selectivity and decreases energy consumption at the same time. The inlet ethylene flow rate of each alkylation reactor is optimized in order to reduce the chance of transalkylation reactions but increase ethylbenzene selectivity. The byprodu...